RUTHERFORD’S ATOMIC MODEL – THE NUCLEAR ATOM
Rutherford proceeded to perform experiments to know as to how
and where these electrons and a positive ion were located in the atom.
Rutherford’s atomic model became known as the nuclear model. In
the nuclear atom, the protons and neutrons, which comprise nearly all of the
mass of the atom, are located in the nucleus at the center of the atom. The
electrons are distributed around the nucleus and occupy most of the volume of
the atom.
In 1909 Rutherford and Marsden performed their historic Alpha Particle-Scattering Experiment, using the apparatus illustrated in Figure.
Rutherford and Marsden noticed that most of the α-particles passed straight through the gold foil and thus produced a flash on the screen behind it. This indicated that gold atoms had a structure with plenty of empty space. To their great astonishment, tiny flashes were also seen on other portions of the screen, sometime in front of the gold foil.
This showed that gold atoms deflected or ‘scattered’ α-particles
through large angles so much so that some of these bounced back to the source.
Based on these observations, Rutherford proposed a model of the
atom which is named after him. This is also called the Nuclear Atom.
According to it
·
Atom has a tiny dense central core or the
nucleus which contains practically the entire mass of the atom, leaving the
rest of the atom almost empty. The diameter of the nucleus is about 10–13 cm as
compared to that of the atom 10– 8 cm. If the nucleus were the size of a
football, the entire atom would have a diameter of about 5 miles. It was this
empty space around the nucleus which allowed the α-particles to pass through undeflected.
·
The entire positive charge of the atom is
located on the nucleus, while electrons were distributed in vacant space around
it. It was due to the presence of the positive charge on the nucleus that
α-particle (He2+) were repelled by it and scattered in all directions.
·
The electrons were moving in orbits or closed
circular paths around the nucleus like planets around the sun.
Weakness/Drawbacks of Rutherford Atomic Model:
The
assumption that electrons were orbiting around the nucleus was unfortunate.
According to the classical electromagnetic theory if a charged particle
accelerates around an oppositely charged particle, the former will radiate
energy. If an electron radiates energy, its speed will decrease and it will go
into spiral motion, finally falling into the nucleus. This does not happen
actually as then the atom would be unstable which it is not. This was the chief
weakness of Rutherford’s Atomic Model.
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Reference:
Essentials of Physical Chemistry by B.S. Bahl

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